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Beilstein J. Org. Chem. 2007, 3, No. 48, doi:10.1186/1860-5397-3-48
Graphical Abstract
Figure 1: Ruthenium based precatalysts used in this study.
Scheme 1: RORCM of 2-azabicycloalkenes 5 to bicyclic scaffolds 6.
Scheme 2: RORCM of 7-azabicycloalkenes 8 and 10 to pyridone 9 and isoindole scaffold 11.
Scheme 3: RORCM of 7-azabicycloalkenes 13 and 16 to bicyclic scaffolds 14, 15, 17 and 18. Conditions A: 10 mo...
Scheme 4: ROCM of 7-azabicycloalkenes 7 and 12 to isoindole and pyrrolidine scaffolds 19 and 20.
Scheme 5: Catalytic enantioselective desymmetrization of 7-azabicycloalkene 10 to scaffold 23.